I knew the ACC would get around to this eventually. The ACC Fall Sports (besides football) TV/Internet schedule is out now:
http://www.theacc.com/#!/news-detail...8-08-13_48z3eu

Here are the Duke events:
Women's Soccer vs Virginia, Thursday, September 26th, 7:00pm, ACC Digital Network
Men's Soccer at UNC, Friday, October 4th, 7:00pm, ESPN3
Volleyball at UNC, Friday, October 11th, 7:00pm, ESPN3
Women's Soccer at Clemson, Thursday, October 17th, 7:00pm, ESPN3
Volleyball at Georgia Tech, Friday, October 18th, 8:30pm, RSN
Women's Soccer vs Pitt, Sunday, October 27th, 1:00pm, RSN
Women's Soccer at UNC, Thursday, October 31st, 7:00pm, ESPN3
Volleyball at Pitt, Sunday, November 10th, 1:00pm, ESPN3

Here they are by Sport:

Men's Soccer:
Friday, October 4th, 7:00pm, ESPN3, at UNC

Women's Soccer:
Thursday, September 26th, 7:00pm, ACC Digital Network, vs Virginia
Thursday, October 17th, 7:00pm, ESPN3, at Clemson
Sunday, October 27th, 1:00pm, RSN, vs Pitt
Thursday, October 31st, 7:00pm, ESPN3, at UNC

Volleyball:
Friday, October 11th, 7:00pm, ESPN3, at UNC
Friday, October 18th, 8:30pm, RSN, at Georgia Tech
Sunday, November 10th, 1:00pm, ESPN3, at Pitt