Football and Basketball will not be the only ACC sports to get some decent coverage on television thanks to the most recent broadcast deal. In the Fall season that means that Field Hockey, Men's and Women's Soccer, and Volleyball will be shown ESPN platforms as well as still to be announced regional cable channels. Soccer games can also be selected as the NSCAA game of the week on Fox Soccer, including tomorrow's men's game when Virginia visits Koskinen Stadium. Here is the Duke list by sport and date for reference. Postseason games will also be broadcast, but I will list the Duke-relevant ones as we get there. Here is the full ACC announcement if you want to see other teams:
http://www.theacc.com/genrel/080511aaa.html

All times Eastern
RSN means cable sports channels that have yet to be announced. ESPN3.com is in the middle of rebranding to WatchESPN.

By Date:
Men's Soccer: vs Virginia, Friday 09/07, 7:00pm, Fox Soccer
Volleyball: @ Wake Forest, Friday 09/16, 7:00pm, RSN
Women's Soccer: vs Virginia, Thursday 09/29, 8:00pm, RSN
Men's Soccer: @ North Carolina, Friday 09/30, 7:00pm, Fox Soccer
Men's Soccer: @ Maryland, Friday 10/14, 7:00pm, ESPN3
Volleyball: vs North Carolina, Wednesday 10/19, 6:00pm, ESPNU
Women's Soccer: @ Wake Forest, Thursday 10/20, 7:00pm, ESPN3
Volleyball: @Georgia Tech, Sunday 10/30, 1:00pm, ESPN3

By Sport:

Volleyball:
@ Wake Forest, Friday 09/16, 7:00pm, RSN
vs North Carolina, Wednesday 10/19, 6:00pm, ESPNU
Volleyball: @Georgia Tech, Sunday 10/30, 1:00pm, ESPN3

Men's Soccer:
vs Virginia, Friday 09/07, 7:00pm, Fox Soccer
@ North Carolina, Friday 09/30, 7:00pm, Fox Soccer
@ Maryland, Friday 10/14, 7:00pm, ESPN3

Women's Soccer:
vs Virginia, Thursday 09/29, 8:00pm, RSN
@ Wake Forest, Thursday 10/20, 7:00pm, ESPN3